Towards Single Atom Catalysis for Environmental Application
Abstract Details:
Various noble metals have been employed as catalysts and co-catalysts to enhance the kinetics of reactions that are critical for environmental remediation. The need to maximize the available catalytic sites per unit mass, particularly due to noble metal scarcity and high cost, has driven the development of material architectures at the nanometer scale. Recent theoretical and experimental studies have explored noble metal catalysts on the sub-nanometer, atomic scale to maximize atomic efficiency. A single atom catalyst (SAC), also called atomically dispersed catalyst, is the theoretical limit in this endeavor, and previous studies have identified additional benefits such as low coordination state and strong interaction with the surrounding substrate resulting in enhanced selective catalysis. For past few years, our group has since been exploring various SACs (Pt, Pd, Ag, and Co) anchored on different substrates (SiC, C3N4, and TiO2) that exhibit unique catalytic properties. This talk summarizes our recent studies to advance the water treatment catalysts from the nano-scale toward the single atom scale such as (1) single-atom Pt and Pd anchored to SiC for selective defluorination of perfluorooctanoic acid (PFOA) and selective dehalogenation of various water pollutants and (2) spatial separation of two co-catalysts by coordinating single atom cobalt at the void center of C3N4 and anchoring anthraquinone at the edges of C3N4 platelets to significantly enhance the catalytic synthesis of H2O2, a precursor chemical for advanced oxidation.
About The Speaker:
Jaehong Kim is currently Henry P. Becton Sr. Professor of Engineering and Department Chair of Chemical and Environmental Engineering in School of Engineering and Applied Science at Yale University. His areas of interest include: 1) environmental application of nanomaterials; 2) development of photoluminescence / photocatalysis technology for environmental and energy application; and 3) membrane process and materials development. Kim received B.S. and M.S. degrees in chemical and biological engineering from Seoul National University in Korea in 1995 and 1997, respectively, and a Ph.D. degree in environmental engineering from the University of Illinois at Urbana-Champaign in 2002. After graduation, he joined the School of Civil and Environmental Engineering at Georgia Institute of Technology where he later held the title of Georgia Power Distinguished Professor and Associate Chair for Undergraduate Programs. He then moved to Yale University in 2013 as Barton L. Weller Endowed Professor. He has taught undergraduate courses such as Water Quality Engineering, Environmental Technology in the Developing World, and Environmental Engineering Laboratory, and graduate courses such as Physicochemical Processes and Design of Drinking Water Treatment Facilities. He is a recipient of various awards including Ackerman Award for Teaching and Mentoring from Yale University (2017), Bill Shultz Junior Faculty Teaching Award from School of Civil and Environmental Engineering (2013), Walter L. Huber Civil Engineering Research Prize from American Society of Civil Engineers (2013), Top Environmental Technology Paper Award from American Chemical Society (2012), Paul L. Busch Award from Water Environment Research Foundation (2009), Excellence in Research Award from Georgia Institute of Technology (2009), and CETL/BP Junior Faculty Teaching Excellence Award from Georgia Institute of Technology (2007).
This webinar is over. You may watch the recorded video in our YouTube page at: https://youtu.be/bkhHDri8rB8
—
To view all the upcoming seminars, you can visit: https://graphene.nus.edu.sg/news-events/events/
You may also Like & Subscribe our following channels below to receive instant notifications for new announcements.