Li, Qi; Zhao, Xiaoxu; Deng, Longjiang; Shi, Zhongtai; Liu, Sheng; Wei, Qilin; Zhang, Linbo; Cheng, Yingchun; Zhang, Li; Lu, Haipeng; Gao, Weibo; Huang, Wei; Qiu, Cheng-Wei; Xiang, Gang; Pennycook, Stephen John; Xiong, Qihua; Loh, Kian Ping; Peng, Bo Enhanced Valley Zeeman Splitting in Fe-Doped Monolayer MoS2 Journal Article 85 ACS NANO, 14 (4), pp. 4636-4645, 2020, ISSN: 1936-0851. Abstract | Links | BibTeX @article{ISI:000529895500083,
title = {Enhanced Valley Zeeman Splitting in Fe-Doped Monolayer MoS_{2}},
author = {Qi Li and Xiaoxu Zhao and Longjiang Deng and Zhongtai Shi and Sheng Liu and Qilin Wei and Linbo Zhang and Yingchun Cheng and Li Zhang and Haipeng Lu and Weibo Gao and Wei Huang and Cheng-Wei Qiu and Gang Xiang and Stephen John Pennycook and Qihua Xiong and Kian Ping Loh and Bo Peng},
doi = {10.1021/acsnano.0c00291},
times_cited = {85},
issn = {1936-0851},
year = {2020},
date = {2020-04-28},
journal = {ACS NANO},
volume = {14},
number = {4},
pages = {4636-4645},
publisher = {AMER CHEMICAL SOC},
address = {1155 16TH ST, NW, WASHINGTON, DC 20036 USA},
abstract = {The "Zeeman effect" offers unique opportunities for magnetic manipulation of the spin degree of freedom (DOF). Recently, valley Zeeman splitting, referring to the lifting of valley degeneracy, has been demonstrated in two-dimensional transition metal dichalcogenides (TMDs) at liquid helium temperature. However, to realize the practical applications of valley pseudospins, the valley DOF must be controllable by a magnetic field at room temperature, which remains a significant challenge. Magnetic doping in TMDs can enhance the Zeeman splitting; however, to achieve this experimentally is not easy. Here, we report unambiguous magnetic manipulation of valley Zeeman splitting at 300 K (g(eff) = -6.4) and 10 K (g(eff) = -11) in a CVD-grown Fe-doped MoS2 monolayer; the effective Lande g(eff )factor can be tuned to -20.7 by increasing the Fe dopant concentration, which represents an approximately 5-fold enhancement as compared to undoped MoS2. Our measurements and calculations reveal that the enhanced splitting and gaff factors are due to the Heisenberg exchange interaction of the localized magnetic moments (Fe 3d electrons) with MoS2 through the d-orbital hybridization.},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
The "Zeeman effect" offers unique opportunities for magnetic manipulation of the spin degree of freedom (DOF). Recently, valley Zeeman splitting, referring to the lifting of valley degeneracy, has been demonstrated in two-dimensional transition metal dichalcogenides (TMDs) at liquid helium temperature. However, to realize the practical applications of valley pseudospins, the valley DOF must be controllable by a magnetic field at room temperature, which remains a significant challenge. Magnetic doping in TMDs can enhance the Zeeman splitting; however, to achieve this experimentally is not easy. Here, we report unambiguous magnetic manipulation of valley Zeeman splitting at 300 K (g(eff) = -6.4) and 10 K (g(eff) = -11) in a CVD-grown Fe-doped MoS2 monolayer; the effective Lande g(eff )factor can be tuned to -20.7 by increasing the Fe dopant concentration, which represents an approximately 5-fold enhancement as compared to undoped MoS2. Our measurements and calculations reveal that the enhanced splitting and gaff factors are due to the Heisenberg exchange interaction of the localized magnetic moments (Fe 3d electrons) with MoS2 through the d-orbital hybridization. |
